Decouverte

1808 · 42218 — London W. Bulmer and Co. 1808. 4to. No wrappers as extracted from "Philosophical Transactions" 1808 - Part I. Pp. 1-44. <br/><br/><em>First printing of this importent historical paper in chemistry in which Davy shows that electricity is capable of decomposing some alkalies isolating two new substances and discovering potassium and sodium. Neville in his Historical Chemical Library vol. I p.340 writes about this paper "ONE OF THE GREAT CLASSIC RESEARCHES IN CHEMISTRY in which Davy announced in this his second Bakterian lecture the isloation of metallic potassium and sodium by the electrolytic decomposition of their fused oxides.""He Davy began his own electrical experiments.The results were spectacular. On October 6 1807 the current passing through molten potash liberated a metal which Davy called potassium. The little globules of shining metal tore the water molecule apart as it eagerly recombined with oxygen and the liberated hydrogen burst into lavender flame. Davy danced about in a delirium of joy. A week later he isolated sodium from soda."Asimow. The paper offered here describes these discoveries."Humphry Davy was one of the most brilliant chemists of the early nineteenth century. His early study of nitrous oxide brought him his first reputation but his later and most importent investigations were devoted to electrochemistry. Following Galvani's experiments and the discovery of the voltaic pile interest in galvanic electricity had become widespread. The first electrolysis by means of the pile was carried out in 1800 by Nicholson and Carisle who obtained oxygen and hydrogen from water. Davy began to examine the chemical effects of electricity in 1800 and his numerous discoveries were presented in his Bakerian lecture to the Royal Society on November 20 1806.A Source Book in Chemistry p. 243. - Wheeler Gift: 2514. </em> unknown